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Project Gutenberg's Encyclopedia, vol. 1 ( A - Andropha

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be composed of olein, that is to say, the triglyceride of 
oleic acid, with small quantities of impurities; chemists, 
therefore, to distinguish oils of various origin, confined 
themselves to tests for these impurities, employing so-called 
colour reactions based upon the change of colour of the oil 
by various reagents such as sulphuric, nitric or phosphoric 
acids.  These reactions were exceedingly indefinite and 
unsatisfactory and oil adulteration was prevalent and almost 
undiscoverable.  It has been found, however, that the old 
ideas concerning the believed uniformity in the nature and 
constitution of oils were erroneous.  Some oils, indeed, do 
consist of olein, almond oil being a type, others contain a 
glyceride of an acid which is distinguished from oleic acid 
by containing one molecule less hydrogen, called linoleic 
acid.  To this class belong cotton-seed and sesame oils.  
Others again include a glyceride of an acid containing still 
less hydrogen, linolenic acid (linseed and similar drying 
oils), and lastly the liver oils are still poorer in hydrogen.  
These various acids or the oils contained in them combine with 
various percentages of iodine, oleic acid absorbing the smallest 
proportion (about 80%); For each oil the iodine absorption 
is a fairly constant quantity; this number, together with 
the determination of the amount of caustic alkali needed for 
complete saponification, the thermal rise with strong sulphuric 
acid or with bromine, the refraction of light and the specific 
gravity, now enable the analyst to form a fair idea of the 
nature of any sample under examination, and, in consequence 
of this advance in knowledge, adulteration of oils has much 
declined.  The most common adulterant of the more valuable 
oils, like olive oil, is cotton-seed oil.  The oils expressed 
from the sesame seed or the earth-nut (arachis oil) are also 
frequently admixed with olive oil.  Almond oil is adulterated 
with the closely allied oils from the peach-kernel or the 
pine-seed.  Deodorized paraffin hydrocarbons also enter 
sometimes as adulterants into edible oils.  There is, 
however, a marked improvement in the purity of oils generally. 
Flour and bread as sold in England are almost invariably 
genuine.  The old forms of adulteration, such as the use of 
alum for the production of a white but indigestible loaf from 
bad flour, have disappeared.  The only admixture which has 
been met with during recent years is maize-meal in American 
produce.  This is of inferior food value to wheat-meal. 

Sugar in its various forms can hardly be said to be subject 
to adulteration by the addition of inferior substitutes.  One 
single case of such substitution analogous to the proverbial 
but probably mythical sanding of sugar occurred between 
1880 and 1905 in England, some crushed marble having been 
found in a consignment of German sugar in a large British 
establishment.  There have, however, been numerous prosecutions 
for a fraud of another class, namely, the substitution 
of dyed beetroot sugar for Demerara sugar.  Formerly the 
sugar produced by the old imperfect and wasteful methods of 
manufacture was more or less yellow or brown from adhering 
molasses.  Sugar, as now obtained, be it from cane or beet, is 
white; yet the public is so wedded to its customs that white 
sugar except as lump or castor sugar does not,find a ready 
sale.  The manufacturer is obliged to colour his product yellow 
by artificial means, that is to say, either by the addition of 
a little aniline dye, harmless in itself, or, as in the West 
Indies, mostly by the use of a small quantity of chloride 
of tin, so-called ``bloomer.'' European refined beet-sugar 
coloured with aniline dye to distinguish it from Demerara cane 
sugar is sold under the name of ``yellow crystals.'' These, 
although richer in real sugar than Demerara, are without the 
delicious aroma of cane syrup which belongs to the latter, and 
are not infrequently fraudulently substituted for Demerara. 

Marmalade and Jams.---In the preparation of marmalade 
and jams, which articles were for a long time mado from 
fruit and sugar only, a part of the sugar, from 10 to 15%, 
is often now replaced by starch glucose.  This material, 
consisting mainly of a mixture of dextrose and dextrin, is 
of much less sweetening power than ordinary sugar and mostly 
cheaper.  It is said to prevent the crystallization which 
frequently used to occur in some jams.  The use of glucose 
has been declared by the High Court (Smith v. Wisden, 
1901) to be legitimate, the court holding that as there was 
no recognized standard for the composition of marmalade the 
addition of saccharine material not injurious to health could 
not constitute an offence.  Artificial colouring matters and 
chemical preservatives are almost constant ingredients of 
jams.  To such fruits which, when boiled with sugar, do 
not readily yield a jelly (strawberries, raspberries) 
an addition of apple juice is frequently made in the 
manufacture of jam, without much objection; the pulp of the 
apple, however, is sometimes bodily added as an adulterant. 

Tea.---In consequence of the proviso contained in the Food 
Act of 1875 that tea was to be examined by the Customs on 
importation, such tea as was found to be admixed with other 
substance or exhausted tea being refused entry into England, 
the adulteration of tea has been virtually suppressed.  Great 
numbers of samples are annually examined by the Customs, 
and a not inconsiderable proportion of these are condemned 
because they are either damaged or dirty, their use for 
the manufacture of theine being permitted, only sound and 
genuine tea coming to the British public.  The practice, very 
common a generation ago, of artificially colouring tea green 
with, a mixture of Prussian blue and turmeric, has quite 
vanished with the decline of the consumption of green tea. 

Coffee.---A few cases of artificially manufactured coffee 
berries, made from flour and chicory, have been observed, but 
it would not be fair to speak of a practice of adulteration 
regarding coffee berries.  Not infrequently coffee is roasted 
with the addition of some fatty matter or paraffin or sugar, 
to give to the roasted coffee a glossy appearance.  These 
additions as a rule are small in amount.  Ground coffee is 
often sold adulterated with chicory, sugar or caramel.  Other 
adulterations, reference to which is found in literature relating 
to the second half of the 19th century, do not seem now to occur. 

Cocoa and chocolate are liable to a number of fraudulent 
or questionable additions.  In the cheaper qualities of 
cocoa-powder sugar and starch--the latter in the form 
of sago flour or arrowroot--are admixed in very large 
proportions, and, in order to give to such mixtures something 
like the appearance of genuine cocoa, red oxide of iron is 
added.  This almost invariably is more or less arsenical.  
Cocoa-shell, a perfectly valueless material, is mixed in a 
very finely ground state with cocoa of the commoner kind.  
Owing to the enormous increase in the consumption of so-called 
chocolate-creams, which are masses of sugar confectionery 
coated with a cocoa-paste containing a large proportion of 
the fat of cocoa (cocoa-butter), the quantity of cocoa-butter 
that is obtained in the manufacture of cocoa-powders is 
no longer sufficient to cover the demand.  Substitutes of 
cocoa-butter prepared from cocoa-nut oil are manufactured 
on a large scale, and all enter without acknowledgment 
into chocolates or chocolate creams.  As there are not any 
regulations touching the composition of chocolate, sugar 
or starch or both are used in chocolate manufacture, and 
especially in that of chocolate powders in often excessive 
quantities.  In the Dutch mode of manufacture of cocoa-powders 
an addition of from 3% to 4% of an alkaline salt is made 
for the purpose of rendering the cocoa ``soluble,'' or, more 
strictly, for putting it into such a physical condition that 
it does not settle in the cup.  This addition does not, as 
is often alleged, render the cocoa alkaline, and is not made 
with any fraudulent object; several countries, however, have 
passed regulations fixing the maximum of the addition which 
may thus legitimately be made.  Most of the cocoa powders sold 
in England are prepared in accordance with the Dutch method. 

Wine.--If under this term a beverage is understood which 
consists of nothing but fermented grape juice, a great 
proportion of the wine consumed in England is not genuine 
wine.  All port and sherry comes into commerce after 
having received an addition of spirit, generally made from 
potatoes; port and sherry would not be what they are and 
as they have been for generations unless they were thus 
fortified.  The practice can now hardly be classed among 
adulterations.  A well-fermented wine made from the juice 
of properly matured grapes does not require any added 
alcohol in order that it should keep; imperfectly made wine 
is liable to turn sour; the addition of alcohol prevents 
this.  French wines, both red and white, are hardly subject to 
adulteration.  In wine-growing countries like France wine is so 
cheap and plentiful that it would be difficult to manufacture 
an imitation beverage cheaper than genuine wine.  In Germany 
the conditions are different, the districts from which those 
wines that are exported are nominally derived being small and 
insufficient to cover the world's demands.  The addition of 
sugar solution or of starch sugar is allowed within limits 
by German law, which not even requires that notification to 
the purchaser be made of the addition, and it is notorious 
that a very large proportion of the wine sold under the name 
of ``hock'' and some of that coming from the Moselle are 
thus diluted, sugared and lengthened, or, in plain terms, 
adulterated.  Wines from the Palatinate which under their own 
names would not sell out of Germany are often passed off as 
hocks.  As there is but little German red wine the law 
also permits this to be lengthened by the addition of white 
wine.  For the removal of part of the acid from sour wine 
produced in bad vintages the addition of precipitated chalk 
is also permitted.  Attention has been drawn in England to 
the very serious fact that German wines sometimes contain 
salts of zinc in small quantities.  These are introduced by 
a fining agent protected by a German patent, consisting of 
solutions of sulphate of zinc and potassium ferrocyanide, 
which, when added together in ``suitable proportions,'' 
produce a precipitate of zinc-ferrocyanide which carries down 
all turbidity in the wine and is supposed to leave neither 
zinc nor ferrocyanide behind in solution.  As a matter of 
fact, one or other of these highly objectionable substances 
is almost invariably left behind.  The use of artificial 
colouring matters in wines does not appear now to occur. 

Beer cannot be said to be adulterated, although it is well 
known that materials often very different from these which the 
general public believe to be the proper raw materials for the 
manufacture of beer, namely, water, malt and hops, are largely 
used.  By the Customs and Inland Revenue Act 1885, sec. 4, 
beer is defined as any liquor ``which is made or sold as a 
description of beer, or as a substitute for beer, and which 
on analysis of a sample thereof shall be found to contain more 
than 2% of proof spirit.'' That is to say, beer is legally 
anything that is sold as beer provided that it has 2% of proof 
spirit.  There is not any restriction upon the materials 
that are employed provided that they are not positively 
poisonous.  For Inland Revenue purposes, however, a prohibition 
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